Bolaform and classical cationic metallomicelles as catalysts of the cleavage of p-nitrophenyl picolinate

R Fornasier, P Scrimin, P Tecilla…

Index: Fornasier, Roberto; Scrimin, Paolo; Tecilla, Paolo; Tonellato, Umberto Journal of the American Chemical Society, 1989 , vol. 111, # 1 p. 224 - 229

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Citation Number: 99

Abstract

Results Synthesis and Properties of the Ligands. Surfactants 1, 3, and 5 and models 2, 4, and 6 were all synthesized from 2-(bromo-rnethyl)-6-(hydro~ ymethyl) pyridine'~ as a common precursor as outlined in Scheme I. Compounds 1 and 2 were obtained by Gabriel reaction followed by acylation with acetyl chloride (2) or w-bromododecyl chloride and quaternization with trimethylamine (1). Model compound 4 was synthesized by reaction of ...