Improved large scale synthesis of 2-trimethylsiloxy-1, 3-butadiene

RT Uyeda, P Vu, DD Holsworth

Index: Uyeda, Roy T.; Vu, Phong; Holsworth, Daniel D. Organic Preparations and Procedures International, 2002 , vol. 34, # 5 p. 540 - 543

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Abstract

We recently required multigram quantities of 2-trimethylsiloxy-l, 3-butadiene (l), a versatile Diels-Alder reaction component used to synthesize a number of ring systems, including substituted pyranones,'pyridones? and cyclohexanones.'A number of methods exist for the synthesis of this compound, 3 the procedure outlined by Jung4 being the most convenient. Although, Jung's procedure

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