The Journal of Organic Chemistry

The Condensation Products of Aldehydes and Aldol-sensitive β-Dicarbonyl Compounds1a

BD Wilson

Index: Wilson,B.D. Journal of Organic Chemistry, 1963 , vol. 28, p. 314 - 320

Full Text: HTML

Citation Number: 34

Abstract

H, CO+ 2 CH3COCHzCOOCzHj acetoacetate and formalin, as reported by Rabe, lb appears to be in error. The condensation does not give both diethyl a, a'-diacetylglutarate (I) and 4, 6- di-carbethoxy-3-hydroxy-3-methylcyclohexanone (11). A careful translation of Rabe's article^'^^^ indicates that I is the sole product, that it is completely stable, and that it is converted to 11, its intramolecular aldol product, only on the introduction of amine bases. ...

Related Articles:

Facile eco-friendly synthesis of novel chromeno [4, 3-b] pyridine-2, 5-diones and evaluation of their antimicrobial and antioxidant properties

[Jaggavarapu, Satyanarayana Reddy; Kamalakaran, Anand Solomon; Jalli, Ventkata Prasad; Gangisetty, Sravan Kumar; Ganesh, Munusswamy Ramanujam; Gaddamanugu, Gopikrishna Journal of Chemical Sciences, 2014 , vol. 126, # 1 p. 187 - 195]

Alkaline polymerization of 6-caprolactam. XXII. Preparation and properties of some N-alkylacetoacetamides and their hydrolysis in acid and alkaline media

[Bukac,Z.; Sebenda,J. Collection of Czechoslovak Chemical Communications, 1966 , vol. 31, p. 3315 - 3330]

More Articles...