Syntheses, reactions, and molecular structures of trans-hydrido (phenylamido) bis (triethylphosphine) platinum (II) and trans-hydridophenoxobis (triethylphosphine) …

RL Cowan, WC Trogler

Index: Cowan, Robert L.; Trogler, William C. Journal of the American Chemical Society, 1989 ,  vol. 111,  # 13  p. 4750 - 4761

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Citation Number: 161

Abstract

Abstract: The reaction between trans-PtH (NO,)(PEt,), and NaNHPh in C6H6 yields the novel hydridoamido complex trans-PtH (NHPh)(PEt,),(I). This compound is stable in solution; however, crystals of I decompose within hours at room temperature. At-100'C a crystal of I belongs to the monoclinic space group P21/n with a= 11.445 (2) A, b= 13.010 (2) A, c= 14.888 (2) A,/3= 104.63 (I)', V= 2144.9 (6) A,, and Z= 4. Complex I adopts a trans structure, ...