Reaction of Tricoordinate Phosphorus Compounds with Pseudohalogens. Scope and Mechanism

A Skowrońska, E Krawczyk, J Burski

Index: Skowronska, Aleksandra; Krawczyk, Ewa; Burski, Janusz Phosphorus and Sulfur and the Related Elements, 1983 , vol. 18, p. 233 - 236

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Citation Number: 14

Abstract

Abstract The selectivity of sulphur, selenium and oxygen removal from pseudohalogens: phosphorus disulphides 1 and 2, diselenides 3 and oxophosphoranesulphenyl chlorides 4 has been investigated. A mechanistic rationalization is proposed to account for sulphur (selenium)/oxygen extrusion variation as a function of substrates structure and reaction conditions.

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