Oligosaccharide synthesis based on glycosyl donors and acceptors carrying phosphorus-containing leaving groups

S Hashimoto, H Sakamoto, T Honda, S Ikegami

Index: Hashimoto, Shun-Ichi; Sakamoto, Hiroki; Honda, Takeshi; Ikegami, Shiro Tetrahedron Letters, 1997 , vol. 38, # 29 p. 5181 - 5184

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Citation Number: 33

Abstract

Efficient synthetic strategy for oligosaccharides has been developed by exploiting the difference in anomeric reactivity between glycosyl donors and acceptors carrying phosphorus-containing leaving groups, wherein the tetramethylphosphoroamidate group plays a pivotal role as anomeric protective group as well as leaving group.