Activation of the N CH bond of Morita-Baylis-Hillman adducts of N-substituted isatins with cerium ammonium nitrate (CAN) and alcohol (ROH)

P Shanmugam…

Index: Shanmugam, Ponnusamy; Vaithiyanathan, Vadivel Canadian Journal of Chemistry, 2009 , vol. 87, # 4 p. 591 - 599

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Abstract

A study on the activation of the N CH bond of Morita-Baylis-Hillman adducts of N-substituted isatin with cerium ammonium nitrate (CAN) and saturated and unsaturated alcohols have been carried out. The choice of a Morita-Baylis-Hillman adduct for this study is screened with a number of adducts. A comparative and reactivity pattern study on N CH activation of Morita- Baylis-Hillman adducts of N-substituted isatin derivatives viz. N-methyl, N-ethyl, N-methyl ...