Green Chemistry

PdCl 2 (py) 2 encaged in monodispersed zeolitic hollow spheres: a highly efficient and reusable catalyst for Suzuki–Miyaura cross-coupling reaction in aqueous …

Z Guan, J Hu, Y Gu, H Zhang, G Li, T Li

Index: Guan, Zhenhong; Hu, Jianglin; Gu, Yanlong; Zhang, Haojun; Li, Guangxing; Li, Tao Green Chemistry, 2012 , vol. 14, # 7 p. 1964 - 1970

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Citation Number: 37

Abstract

By encaging the PdCl2 (py) 2 complex (py= pyridine) in the interior space of silicalite-1 hollow spheres (SHS), a novel solid palladium catalyst, PdCl2 (py) 2@ SHS, was successfully prepared. The structure and composition of the solid catalyst was characterized by SEM, TEM, XRD, N2 sorption, FT-IR and XPS. This catalyst afforded fast conversions for the Suzuki–Miyaura cross-coupling reactions of various aryl halides and arylboronic acids ...

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