Addition of Silicon Hydrides to Olefinic Double Bonds. VII. Addition to Chloro-and Dichlorobutenes

AG Smith, JW Ryan, JL Speier

Index: Smith,A.G. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 2183 - 2186

Full Text: HTML

Citation Number: 21

Abstract

In the presence of platinum catalysts, silicon hydrides react with allylic chlorides in a highly complex way. The products obtained from 1-chlorobutene-2, 3-chlorobutene-1, 1, 4dichlorobutene-2, and 3, 4dichlorobutene-2 were found to include numerous compounds, The formation of the various compounds is explained as due to a series of allyl rearrangements, eliminations of chloride from allylic chlorides and double bond ...