Reaction of Phenanthrene??9, 10??dione with Phenanthrene??9, 10??diol: Synthesis and Characterization of the First ortho??Quinhydrone Derivative
…, F Marchetti, G Pampaloni, L Pieretti
Index: Calderazzo, Fausto; Forte, Claudia; Marchetti, Fabio; Pampaloni, Guido; Pieretti, Laura Helvetica Chimica Acta, 2004 , vol. 87, # 4 p. 781 - 789
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Citation Number: 15
Abstract
Abstract Treatment of phenanthrene-9, 10-dione (PQ) with phenanthrene-9, 10-diol (PQH 2), as prepared by catalytic hydrogenation of PQ, in toluene solution or in the solid state afforded crystalline '9, 10-phenanthrenequinhydrone'(PQH), the first example of an ortho- quinhydrone. PQH was characterized by analytical and spectroscopic methods, including X- ray and CP/MAS 13 C-NMR analyses. The crystal structure of PQH showed pairs of planar ...
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