Structural effects upon catalysis by cationic micelles

CA Bunton, LB Robinson…

Index: Bunton,C.A. et al. Journal of Organic Chemistry, 1970 , vol. 35, p. 108 - 114

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Citation Number: 29

Abstract

The catalytic efficiencies of phenyl-and 2, 4-dimethoxyphenylcetyldimethylammonium bromides (CPDA and CDPDA) are greater than that of cetyltrimethylammonium bromide (CTABr) for the spontaneous hydrolyses of the dianions of 2, 4-and 2, 6-dinitrophenyl phosphates, the reactions of hydroxide and fluoride ions with p-nitrophenyl diphenyl phosphate, and the reaction of hydroxide ion with 2, 4-dinitrochlorobenzene in water, ...