The sulfuranyl radical structure and reactions of o-(thio) benzoyloxyl radicals formed by the decomposition of t-butyl o-(thio)-perbenzoates studied by 1H and 13C …
W Nakanishi, Y Kusuyama, Y Ikeda…
Index: Nakanishi; Kusuyama; Ikeda; Iwamura Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 10 p. 3123 - 3128
Full Text: HTML
Citation Number: 2
Abstract
1 H and 13 C CIDNP signals were observed in the methyl group of o-(methylthio) benzoic acid and the methylene group of 3, 1-benzoxathian-4-one (6) during the thermal decomposition of t-butyl o-(methylthio) perbenzoate. The results show that the free “o- (methylthio) benzoyloxyl radical” itself is better represented as the bridged sulfuranyl radical in which most of the spin density is localized at the sulfur atom rather than in the carboxyl. ...
Related Articles:
[Uchida, Yuzuru; Kobayashi, Yusho; Kozuka, Seizi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 6 p. 1781 - 1786]
[Uchida, Yuzuru; Kobayashi, Yusho; Kozuka, Seizi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 6 p. 1781 - 1786]
[Uchida, Yuzuru; Kobayashi, Yusho; Kozuka, Seizi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 6 p. 1781 - 1786]
[Uchida, Yuzuru; Kobayashi, Yusho; Kozuka, Seizi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 6 p. 1781 - 1786]
[Uchida, Yuzuru; Kobayashi, Yusho; Kozuka, Seizi Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 6 p. 1781 - 1786]