Journal of the American Chemical Society

Selective Reduction of Aliphatic Nitroesters with Lithium Aluminum Hydride1

H Feuer, TJ Kucera

Index: Feuer; Kucera Journal of the American Chemical Society, 1955 , vol. 77, p. 5740

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Citation Number: 11

Abstract

The selective reduction of ethyl fi-nitrobenzoate and ethyl P-nitrophenylacetate to the corresponding nitroalcohols with lithium aluminum hydride at 25" has been reported by Felkk2 We wish to report the successful reduction of aliphatic nitroesters, containing a secondary, tertiary or gem-dinitro group, to the corresponding nitrocarbinols in yields which compare favorably with those obtained by the reduction of aliphatic nitroaldehydes with ...