Bis [2] catenanes and a bis [2] rotaxane–Model Compounds for Polymers with Mechanically Interlocked Components

PR Ashton, J Huff, S Menzer, IW Parsons…

Index: Ashton, Peter R.; Huff, Juergen; Menzer, Stephen; Parsons, Ian W.; Preece, Jon A.; et al. Chemistry--A European Journal, 1996 , vol. 2, # 1 p. 31 - 44

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Citation Number: 90

Abstract

Abstract The self-assembly of three bis [2] catenanes and a bis [2] rotaxane, by two complementary strategies, is reported. A synthetic route to derivatives of bis-para-phenylene [34] crown-10 (BPP34C10) and 1, 5-naphtho-para-phenylene [36]-crown-10 (1/5NPP36C10) containing a fused five-membered ring with a secondary amine function is described. These intermediate N-allylimido macrocyclic polyethers undergo template- ...

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