Tetrahedron letters

Construction of bicyclo [2.2. 2] octane ring system via homoallyl-homoallyl radical rearrangement

M Toyota, M Yokota, M Ihara

Index: Toyota, Masahiro; Yokota, Masahiro; Ihara, Masataka Tetrahedron Letters, 1999 , vol. 40, # 8 p. 1551 - 1554

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Citation Number: 36

Abstract

We designed a sequential three-step, one-pot reaction (homoallyl-homoallyl radical rearrangement reaction) to generate highly functionalized bicyclo [2.2. 2] octane ring system, and succeeded in developing a novel synthetic method to bicyclo [2.2. 2] octane compounds from simple cyclohexene derivatives.