Tetrahedron: Asymmetry

Synthesis of novel chiral lipophilic pyridyl-containing β-amino alcohol ligands and enantioselective hydrolysis of α-amino acid esters by chiral metallomicelles

J You, X Yu, K Liu, L Tao, Q Xiang, R Xie

Index: You, Jingsong; Yu, Xiaoqi; Liu, Ke; Tao, Lin; Xiang, Qingxiang; Xie, Rugang Tetrahedron Asymmetry, 1999 , vol. 10, # 2 p. 243 - 254

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Citation Number: 33

Abstract

Seven novel chiral lipophilic pyridyl-containing β-amino alcohol ligands have been synthesized by coupling of 6-alkoxymethyl-2-chloromethylpyridine 3 with the corresponding chiral β-amino alcohols or l-cysteine. Their metal ion complexes have been investigated as catalysts for the enantioselective hydrolysis of N-protected α-amino acid esters in aqueous comicellar solution. The results indicate that the hydrophobic interactions between ...

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