Journal of Fluorine Chemistry

Electrofluoration en position benzylique dans le sulfolane

E Laurent, B Marquet, R Tardivel

Index: Laurent, Eliane; Marquet, Bernard; Tardivel, Robert Journal of Fluorine Chemistry, 1990 , vol. 49, # 1 p. 115 - 126

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Citation Number: 23

Abstract

Abstract The use of sulfolane as a solvent instead of acetonitrile in the electrofluorination of benzylic derivatives1,(R= H, Cl) gives greater yields of benzylic fluorides 2, since the formation of acetamido byproducts 4 is prevented. However, the parallel fluorination of the aromatic nucleus is not avoided under these conditions.

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