Copper??Catalyzed Intramolecular C–H Amination

DN Barman, KM Nicholas

Index: Barman, Dipti N.; Nicholas, Kenneth M. European Journal of Organic Chemistry, 2011 , # 5 p. 908 - 911

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Citation Number: 20

Abstract

Abstract The amino-functionalization of tertiary, secondary and benzylic C–H bonds of tethered carbamates and sulfamates by iodosobenzene is catalyzed by Cu I-diimine complexes in moderate to good yield. Employing homochiral imine-Cucatalysts affords oxazolidinones and oxathiazinanes with modest enantioselectivity.

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