Functionally substituted organotin compounds I. Addition of thiols to alkenyltin compounds

G Ayrey, RD Brasington, RC Poller

Index: Ayrey, G.; Brasington, R. D.; Poller, R. C. Journal of Organometallic Chemistry, 1972 , vol. 35, p. 105 - 109

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Citation Number: 10

Abstract

Abstract 3-(Trialkylstannyl) propyl aryl sulphides (R 3 SnCH 2 CH 2 CH 2 SR′; R= Me, Et, Bu; R′= Ph, p-tolyl) were prepared by the addition of arenethiols to allyltrialkyltin compounds. Preferential cleavage of the allyl group by the reaction R 3 SnCH 2 CH CH 2+ R′ SH→ R 3 SnSR′+ CH 3 CH CH 2 occurred when R= R′= Bu and R= R′= Ph. Diallyltin dibromide and benzenethiol gave stannous bromide. Mössbauer parameters of ...