Reactions of 4, 4-Dihydro-3-iodoperfluoroheptane and 2, 2-Dihydro-3-iodoperfluoropentane1, 2

KL Paciorek, BA Merkl, CT Lenk

Index: Paciorek,K.L. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 1015 - 1018

Full Text: HTML

Citation Number: 7

Abstract

thesized initially3 for model studies of the crosslinking mechanism of fluoro elastomer^.^ Subsequent investigations required either a chlorine or a fluorine substituent in place of iodine. Treatment of I with two moles of chlorine at low temperatures resulted in an 83% yield of 4-hydroperfluoroheptene-3 (11). The procedure was a convenient one for dehydrohalogenation. Substitution of the iodine by fluorine was accomplished by heating I ...