Tetrahedron: Asymmetry

Regio-and enantioselective properties of the lipase-catalyzed irreversible transesterification of some 2-substituted-1, 4-butanediols in organic solvents

P Ferraboschi, S Casati, E Verza, E Santaniello

Index: Ferraboschi, Patrizia; Casati, Silvana; Verza, Elisa; Santaniello, Enzo Tetrahedron: Asymmetry, 1995 , vol. 6, # 5 p. 1027 - 1030

Full Text: HTML

Citation Number: 4

Abstract

The regioselectivity of the Pseudomonas fluorescens (P. cepacia) lipase (PFL)-catalyzed irreversible transesterification of 2-substituted-1, 4-butanediols 1a–3a has been studied and, in the case of 3a, it has been shown that (R)-and (S)-diols are acylated with opposite regioselectivity.

Related Articles:

Oxo-tethered ruthenium (II) complex as a bifunctional catalyst for asymmetric transfer hydrogenation and H2 hydrogenation

[Ito, Masato; Ootsuka, Takashi; Watari, Ryo; Shiibashi, Akira; Himizu, Akio; Ikariya, Takao Journal of the American Chemical Society, 2011 , vol. 133, # 12 p. 4240 - 4242]

Hydrogenolysis of succinates and glutarates

[Wojcik; Adkins Journal of the American Chemical Society, 1933 , vol. 55, p. 4943]

Concise synthesis of (+)-β-benzyl γ-butyrolactones from butynediol

[Kamlage; Sefkow; Zimmermann; Peter Synlett, 2002 , # 1 p. 77 - 80]

Oxo-tethered ruthenium (II) complex as a bifunctional catalyst for asymmetric transfer hydrogenation and H2 hydrogenation

[Ito, Masato; Ootsuka, Takashi; Watari, Ryo; Shiibashi, Akira; Himizu, Akio; Ikariya, Takao Journal of the American Chemical Society, 2011 , vol. 133, # 12 p. 4240 - 4242]

More Articles...