The Journal of Organic Chemistry

Synthesis of methylenecycloalkanes from cycloalkenes via borane chemistry

HC Brown, TM Ford

Index: Brown, Herbert C.; Ford, Thomas M. Journal of Organic Chemistry, 1981 , vol. 46, # 3 p. 647 - 648

Full Text: HTML

Citation Number: 11

Abstract

Summary: B-(Cycloalkylmethyl)-9-BBN derivatives, now readily available through the homologation reaction,'are convenient substrates for the synthesis of exocyclic methylene compounds. The method appears to be general. Moreover, since the synthesis proceeds from the cycloalkene, it provides a valuable alternative to the customary methylenation of carbonyl compounds by the Wittig and related procedures. The method also provides a ...

Related Articles:

Group 4 Dimethylsilylenebisamido Complexes Bearing the 6??[2??(Diethylboryl) phenyl] pyrid??2??yl Motif: Synthesis and Use in Tandem Ring??Opening Metathesis/Vinyl …

[Zou, Yuanlin; Wang, Dongren; Wurst, Klaus; Kuehnel, Christa; Reinhardt, Ingrid; Decker, Ulrich; Gurram, Venkatanavarana; Camadanli, Sebnem; Buchmeiser, Michael R. Chemistry - A European Journal, 2011 , vol. 17, # 49 p. 13832 - 13846]

Intramolecular cyclizations of organometallic compounds V. 6, 6-bis (diethylaluminum)-1-hexenes to substituted cyclopentanes.

[Smith, Michael J.; Wilson, Stanley E. Tetrahedron Letters, 1982 , vol. 23, # 48 p. 5013 - 5016]

Deoxygenative coupling of ketones and alkenes by tungsten (II) compounds

[Bryan, Jeffrey C.; Arterburn, Jeffrey B.; Cook, Gerald K.; Mayer, James M. Organometallics, 1992 , vol. 11, p. 3965 - 3970]

Kinetics and regioselectivity of ring opening of 1-bicyclo [3.1. 0] hexanylmethyl radical

[Kantorowski, Eric J.; Le, Daniel D.; Hunt, Caleb J.; Barry-Holson, Keegan Q.; Lee, Jessica P.; Ross, Lauren N. Journal of Organic Chemistry, 2008 , vol. 73, # 4 p. 1593 - 1596]

More Articles...