Hydroperoxylation by hydroxyethylphosphonate dioxygenase

JT Whitteck, RM Cicchillo, WA Donk

Index: Whitteck, John T.; Cicchillo, Robert M.; Van Der Donk, Wilfred A. Journal of the American Chemical Society, 2009 , vol. 131, # 44 p. 16225 - 16232

Full Text: HTML

Citation Number: 32

Abstract

Hydroxyethylphosphonate dioxygenase (HEPD) catalyzes the O2-dependent cleavage of the carbon− carbon bond of 2-hydroxyethylphosphonate (2-HEP) to afford hydroxymethylphosphonate (HMP) and formate without input of electrons or use of any organic cofactors. Two mechanisms have been proposed to account for this reaction. One involves initial hydroxylation of substrate to an acetal intermediate and its subsequent ...

Related Articles:

A Study of the Reaction of Phosphorus Trichloride with Paraformaldehyde in the Presence of Carboxylic Acids

[Troev; Todorov; Naydenova; Mitova; Vassilev Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 9 p. 1147 - 1155]

A Study of the Reaction of Phosphorus Trichloride with Paraformaldehyde in the Presence of Carboxylic Acids

[Troev; Todorov; Naydenova; Mitova; Vassilev Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 9 p. 1147 - 1155]

A Study of the Reaction of Phosphorus Trichloride with Paraformaldehyde in the Presence of Carboxylic Acids

[Troev; Todorov; Naydenova; Mitova; Vassilev Phosphorus, Sulfur and Silicon and the Related Elements, 2013 , vol. 188, # 9 p. 1147 - 1155]

Organische Phosphorverbindungen XXVIII. Die α??Aminoalkylierung von elementarem weissem Phosphor. Eine einfache Methode zur Darstellung von tertiären …

[Maier,L. Helvetica Chimica Acta, 1967 , vol. 50, p. 1723 - 1741]

More Articles...