Inorganic Chemistry 2013-05-06

An asymmetrically derivatized 1,2,3-triphospholide: synthesis and reactivity of the 4-(2'-pyridyl)-1,2,3-triphospholide anion.

Robert S P Turbervill, Jose M Goicoechea

Index: Inorg. Chem. 52(9) , 5527-34, (2013)

Full Text: HTML

Abstract

Reactions between anionic heptaphosphide clusters ([P7](3-)/[HP7](2-)) and 2-ethynylpyridine yielded the 4-(2'-pyridyl)-1,2,3-triphospholide anion ([P3C2H(2-C5H4N)](-); 1). This species was isolated as a compositionally pure [K(2,2,2-crypt)](+) salt in moderate yields. Preliminary coordination studies of 1 toward Mo(CO)6 or Mo(py)3(CO)3 (py = pyridine) afforded the diamagnetic piano-stool complex [{η(5)-P3C2H(2-C5H4N)}Mo(CO)3](-) (2). By contrast, reaction of 1 with Mo(COD)(CO)4 (COD = 1,5-cyclooctadiene) yielded [{κ(2)P,N-P3C2H(2-C5H4N)}Mo(CO)4](-) (3) which readily loses a carbonyl on heating to give 2. Reaction of 2 with Mo(COD)(CO)4 afforded the bimetallic system [{μ:η(5),κ(2)P,N-P3C2H(2-C5H4N)}{Mo(CO)3}{Mo(CO)4}](-) (4).

Related Compounds

  • ethynylpyridine

Related Articles:

Synthesis and properties of an ionic conducting material: in-situ preparation of poly(2-ethynyl-N-iodopyridinium iodide) and its electro-optical and electrochemical properties.

2014-10-01

[J. Nanosci. Nanotechnol. 14(10) , 8028-32, (2014)]

Synthesis and characterization of an ionic conjugated polymer: poly[2-ethynyl-N-(2-furoyl)pyridinium chloride].

2014-08-01

[J. Nanosci. Nanotechnol. 14(8) , 6247-50, (2014)]

Synthesis and properties of a water-soluble ionic conjugated polymer with carboxylic acids.

2012-05-01

[J. Nanosci. Nanotechnol. 12(5) , 4361-4, (2012)]

Uncatalyzed synthesis and characterization of a water-soluble polyacetylene: poly[2-ethynyl-N-(propylsulfonate)pyridinium betaine].

2014-07-01

[J. Nanosci. Nanotechnol. 14(7) , 5480-4, (2014)]

Preparation of the metabotropic glutamate receptor 5 (mGluR5) PET tracer [(18)F]FPEB for human use: An automated radiosynthesis and a novel one-pot synthesis of its radiolabeling precursor.

2014-12-01

[Appl. Radiat. Isot. 94 , 349-54, (2014)]

More Articles...