Catalytic selective deuteration of halo(hetero)arenes.
Manojkumar Janni, S Peruncheralathan
Index: Org. Biomol. Chem. 14 , 3091-7, (2016)
Full Text: HTML
Abstract
Deuterium labeled aromatic and heteroaromatic compounds are synthesized in good to excellent yields with >98% deuterium purity via palladium catalyzed deuterodehalogenation reaction using commercially available and inexpensive reagents. Selective deuteration of bromoaniline is also demonstrated without H/D exchange in an amino N-H group.
Related Compounds
Related Articles:
2015-01-01
[Nat. Commun. 6 , 6579, (2015)]
2014-01-01
[Anal. Sci. 30(12) , 1107-12, (2014)]
2014-06-01
[J. Food Sci. 79(6) , E1150-8, (2014)]
2015-08-28
[J. Chromatogr. A. 1409 , 282-7, (2015)]
2015-09-02
[J. Agric. Food Chem. 63 , 7511-21, (2015)]