" Mercaptan-tail" porphyrins: synthetic analogs for the active site of cytochrome P-450

JP Collman, SE Groh

Index: Collman, James P.; Groh, Susan E. Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1391 - 1403

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Citation Number: 90

Abstract

Abstract: The synthesis and characterization of a series of tetraarylporphyrins which bear covalently attached alkyl and aryl mercaptans designed to serve as axial ligands are described. The coordination chemistry of the iron (I1) complexes of these “mercaptan-tail” porphyrins has been investigated by IH NMR, IR, and electronic absorption spectroscopy, magnetic circular dichroism, and magnetic susceptibility measurements. Ferrous ...