Journal of Catalysis

Manganese (III) porphyrin catalysts for the oxidation of terpene derivatives: a comparative study

V Maraval, JE Ancel, B Meunier

Index: Maraval, Valerie; Ancel, Jean-Erick; Meunier, Bernard Journal of Catalysis, 2002 , vol. 206, # 2 p. 349 - 357

Full Text: HTML

Citation Number: 47

Abstract

A comparative study involving four manganese (III) porphyrin catalysts combined with two different oxidants (sodium hypochlorite and potassium monopersulfate) has been performed in the epoxidation of three terpene derivatives. The catalytic oxidation of α-pinene produces selectively 100% of the epoxide or 65% of allylic oxidation products, only by modification of the substituents on the meso-positions of the metalloporphyrin catalyst. The catalytic ...

Related Articles:

Organic reactions of sulfur dioxide. Reactions with nucleophilic double bonds leading to the isomerization, aromatization, selective hydrogen-deuterium exchange, …

[Masilamani, Divakar; Manahan, Edward H.; Vitrone, John; Rogic, Milorad M. Journal of Organic Chemistry, 1983 , vol. 48, # 25 p. 4918 - 4931]

Microwave-assisted silica-supported aluminum chloride-catalyzed Friedel-Crafts alkylation

[Tetrahedron Letters, , vol. 53, # 39 p. 5343 - 5346]

Efficient synthesis of substituted benzenes from 1, 3-dienes or 1, 4-cyclohexadienes with KMnO 4 under mild conditions

[McBride, Christopher M.; Chrisman, Will; Harris, Clifford E.; Singaram, Bakthan Tetrahedron Letters, 1999 , vol. 40, # 1 p. 45 - 48]

Highly efficient Pd-catalyzed carbonylative cross-coupling reactions with tetraorganoindates

[Journal of Organic Chemistry, , vol. 69, # 14 p. 4852 - 4855]

Highly efficient continuous flow reactions using singlet oxygen as a “green” reagent

[Organic Letters, , vol. 13, # 19 p. 5008 - 5011]

More Articles...