Zinc-catalyzed nucleophilic substitution reaction of chlorosilanes with organomagnesium reagents

K Murakami, H Yorimitsu, K Oshima

Index: Murakami, Kei; Yorimitsu, Hideki; Oshima, Koichiro Journal of Organic Chemistry, 2009 , vol. 74, # 3 p. 1415 - 1417

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Citation Number: 39

Abstract

Zinc-catalyzed nucleophilic substitution reactions of chlorosilanes with organomagnesium reagents afford various tetraorganosilanes under mild reaction conditions. The reactions can be performed on large scale and allow efficient preparation of functionalized tetraorganosilanes.

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