Tetrahedron Letters

Selective cross coupling via oxovanadium (V)-induced oxidative desilylation of benzylic silanes

T Hirao, T Fujii, Y Ohshiro

Index: Hirao, Toshikazu; Fujii, Takashi; Ohshiro, Yoshiki Tetrahedron Letters, 1994 , vol. 35, # 43 p. 8005 - 8008

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Citation Number: 19

Abstract

Abstract Benzylic silanes bearing an electron-donating group at the ortho-or para-position underwent the oxovanadium (V)-induced one-electron oxidative desilylation due to low ionization potential, which was applied to the intermolecular regioselective coupling with allylic silanes or silyl enol ether.

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