Tetrahedron Letters

Direct coupling of nucleophiles with nitroaromatic compounds via fluoride-promoted oxidative nucleophilic aromatic substitution for hydrogen

I Huertas, I Gallardo, J Marquet

Index: Huertas, Inma; Gallardo, Iluminada; Marquet, Jordi Tetrahedron Letters, 2001 , vol. 42, # 20 p. 3439 - 3441

Full Text: HTML

Citation Number: 20

Abstract

Useful yields are achieved in the regioselective direct coupling of amines, amides, and ketones with m-dinitrobenzene, 1-nitronaphthalene, and 1, 3-dinitronaphthalene, through oxidatively activated nucleophilic aromatic substitution for hydrogen promoted by fluoride anions.

Related Articles:

Indium (III) chloride as a new, highly efficient, and versatile catalyst for acylation of phenols, thiols, alcohols, and amines

[Chakraborti, Asit K.; Gulhane, Rajesh Tetrahedron Letters, 2003 , vol. 44, # 35 p. 6749 - 6753]

Mild, Efficient and Selective Nitration of Anilides, Non-Activated and Moderately Activated Aromatic Compounds with Ammonium Molybdate and Nitric Acid as a New …

[Sana, Sariah; Rajanna; Ali, Mir Moazzam; Saiprakash Chemistry Letters, 2000 , # 1 p. 48 - 49]

Nucleophilic aromatic substitution for heteroatoms: an oxidative electrochemical approach

[Huertas, Inma; Gallardo, Iluminada; Marquet, Jordi Tetrahedron Letters, 2000 , vol. 41, # 2 p. 279 - 281]

Mild and selective nitration by claycop

[Gigante, Barbara; Prazeres, Angela O.; Marcelo-Curto, Maria J.; Cornelis, Andre; Laszlo, Pierre Journal of Organic Chemistry, 1995 , vol. 60, # 11 p. 3445 - 3447]

An Effective Method for Acylation of Weakly Nucleophilic Anilines with Silyl Carboxylates via Mixed Anhydrides.

[Miyashita, Mitsutomo; Shiina, Isamu; Mukaiyama, Teruaki Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 1 p. 210 - 215]

More Articles...