Triphenyltin chloride as a new source of phenyl group for C-heteroatom and C–C bond formation

N Iranpoor, H Firouzabadi, EE Davan, A Rostami…

Index: Iranpoor, Nasser; Firouzabadi, Habib; Davan, Elham Etemadi; Rostami, Abed; Nematollahi, Arash Journal of Organometallic Chemistry, 2013 , vol. 740, p. 123 - 130

Full Text: HTML

Citation Number: 11

Abstract

Ph3SnCl is introduced as a very suitable source of phenyl group for coupling with phenols, amines, and thiols in the presence of Cu (OAc) 2 in Et3N at room temperature to give aryl ethers, amines, and arylthio ethers in high yields. In addition, the application of Ph3SnCl in the Stille coupling of aryl halides in the presence of Pd (0) catalyst in PEG 400 at 110° C is discussed.

Related Articles:

Anionic N-fries rearrangement of N-carbamoyl diarylamines to anthranilamides. Methodology and application to acridone and pyranoacridone alkaloids

[MacNeil, Stephen L.; Wilson, Brian J.; Snieckus, Victor Organic Letters, 2006 , vol. 8, # 6 p. 1133 - 1136]

Metal??Free Synthesis of Secondary Arylamines: An Aliphatic??to??Aromatic Transformation

[Barros, M. Teresa; Dey, Suvendu S.; Maycock, Christopher D. European Journal of Organic Chemistry, 2013 , # 4 p. 742 - 747]

Practical copper-catalyzed N-arylation of amines with 20% aqueous solution of n-Bu 4 NOH

[Molaei, Hamidreza; Ghanbari, Mohammad Mehdi Chinese Chemical Letters, 2012 , vol. 23, # 3 p. 301 - 304]

Synthetic methods and reactions. 188. Triflic acid catalyzed phenylamination of aromatics with phenyl azide

[Journal of Organic Chemistry, , vol. 58, # 24 p. 6900 - 6901]

Heteroaromatic-aminomethyl quinolones: Potent and selective iNOS inhibitors

[Bioorganic and Medicinal Chemistry Letters, , vol. 22, # 2 p. 1237 - 1241]

More Articles...