Equilibration of N-(2-cyanoethyl) pyridinium cations with substituted pyridines and acrylonitrile. A change in rate-determining step in an E1cb reaction

JW Bunting, A Toth, CKM Heo…

Index: Journal of the American Chemical Society, , vol. 112, # 24 p. 8878 - 8885

Full Text: HTML

Citation Number: 29

Abstract

... (c) Cockerill, AF; Harrison, R. G. The Chemistry o/ Functional ... 0002-7863/90/15 12-8878$02.50/ 0 I , , 0 1990 American Chemical Society ... This observation lead us to also investigate the rates and equilibria for the Michael-type addition" of a number of pyridinium cations and ...

Related Articles:

Flash vacuum pyrolysis of substituted pyridine N-oxides and its application to syntheses of heterocyclic compounds

[Journal of Organic Chemistry, , vol. 47, # 18 p. 3497 - 3503]

Bifunctional mechanism of pyridine hydrodenitrogenation

[Journal of Catalysis, , vol. 156, # 2 p. 255 - 264]

Dynamics of bond breaking in ion radicals. Mechanisms and reactivity in the reductive cleavage of carbon-fluorine bonds of fluoromethylarenes

[Journal of the American Chemical Society, , vol. 119, # 40 p. 9527 - 9540]

The effects of magnesium2+, hydrogen bonding, and steric factors on rate and equilibrium constants for phosphoryl transfer between carboxylate ions and pyridines

[Journal of the American Chemical Society, , vol. 112, # 5 p. 1942 - 1950]

Effect of neutral pyridine leaving groups on the mechanisms of influenza type A viral sialidase-catalyzed and spontaneous hydrolysis reactions of α-DN- …

[Journal of the American Chemical Society, , vol. 122, # 35 p. 8357 - 8364]

More Articles...