Tetrahedron

α-Nitrocycloalkanones as a Source of α, ω-Dicarboxylic Acid Dimethyl Esters

R Ballini, G Bosica

Index: Ballini, Roberto; Bosica, Giovanna Tetrahedron, 1997 , vol. 53, # 47 p. 16131 - 16138

Full Text: HTML

Citation Number: 16

Abstract

α, ω-Dicarboxylic acid dimethyl esters are casily obtained by ring cleavage of α- nitrocycloalkanones. Thus, reaction of the latter compounds with three equivalents of potassium persulfate, in methanol and in presence of sulfuric acid at 80° C, provides α, ω- dicarboxylic acid dimethyl esters in high yields. Long-chain, and alkylated α, ω-dicarboxylic acid dimethyl esters can be also efficiently obtained.

Related Articles:

Selective esterification of aliphatic nonconjugated carboxylic acids in the presence of aromatic or conjugated carboxylic acids catalysed by NiCl 2. 6H 2 O

[Tetrahedron, , vol. 53, # 21 p. 7335 - 7340]

Cobalt-catalyzed dimerization of alkenes

[Wang, Chun-Chih; Lin, Pao-Shun; Cheng, Chien-Hong Tetrahedron Letters, 2004 , vol. 45, # 32 p. 6203 - 6206]

A unique palladium catalyst for efficient and selective alkoxycarbonylation of olefins with formates

[Fleischer, Ivana; Jennerjahn, Reiko; Cozzula, Daniela; Jackstell, Ralf; Franke, Robert; Beller, Matthias ChemSusChem, 2013 , vol. 6, # 3 p. 417 - 420]

Efficient and selective catalytic oxidative cleavage of α-hydroxy ketones using vanadium-based HPA and dioxygen

[El Aakel; Launay; Atlamsani; Bregeault Chemical Communications, 2001 , # 21 p. 2218 - 2219]

Double Molecular Recognition with Aminoorganoboron Complexes: Selective Alcoholysis of β??Dicarbonyl Derivatives

[Oishi, Shunsuke; Saito, Susumu Angewandte Chemie - International Edition, 2012 , vol. 51, # 22 p. 5395 - 5399]

More Articles...