Inorganic Chemistry 2005-07-25

Structural characterization of the first hydroxo-bridged plutonium compound, (PuO(2))(2)(IO(3))(mu(2)-OH)(3).

Amanda C Bean, Kent Abney, Brian L Scott, Wolfgang Runde

Index: Inorg. Chem. 44(15) , 5209-11, (2005)

Full Text: HTML

Abstract

The hydrothermal reaction of a (239)Pu(IV) stock solution in the presence of iodic acid and 1 M KOH produces reddish-brown single crystals of (PuO(2))(2)(IO(3))(OH)(3). The structure consists of two-dimensional layers forming in the ac plane and is the first single-crystal structure of plutonium(VI) connected through hydroxide anions. The additional linkage of plutonium centers is completed through iodate ligands.

Related Compounds

  • mercuric iodate
  • Iodic acid
  • Potassium hydrogen...
  • magnesium iodate
  • Lithium iodate

Related Articles:

Multiwalled carbon nanotubes dispersed in carminic acid for the development of catalase based biosensor for selective amperometric determination of H(2)O(2) and iodate.

2011-11-15

[Biosens. Bioelectron. 29(1) , 151-8, (2011)]

[Correlation between ERPF and retention function on 131I-OIH renogram].

1984-10-01

[Kaku Igaku. 21(10) , 1285-92, (1984)]

Accounting for changes in particle charge, dry mass and composition occurring during studies of single levitated particles.

2012-10-11

[J. Phys. Chem. A 116(40) , 9941-53, (2012)]

Oxidative stress of human erythrocytes by iodate and periodate. Reversible formation of aqueous membrane pores due to SH-group oxidation.

1984-10-17

[Biochim. Biophys. Acta 777(1) , 107-16, (1984)]

A novel synthesis of 3,5-diiodotyrosine with iodic acid.

1982-02-01

[Anal. Biochem. 120(1) , 204-7, (1982)]

More Articles...