Chemical Communications 2009-10-21

Reactions of (-)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.

Natalie M Clark, Pablo García-Alvarez, Alan R Kennedy, Charles T O'Hara, Gemma M Robertson

Index: Chem. Commun. (Camb.) (39) , 5835-7, (2009)

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Abstract

'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.

Related Compounds

  • Hexamethyldisilaza...
  • Holmium tris(1,1,1...
  • bis(trimethylsilyl...
  • samarium tris(hexa...
  • Tris[N,N-bis(trim...
  • Potassium hexameth...
  • bis(trimethylsilyl...
  • Lithium bis(trimet...
  • Sodium bis(trimeth...

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