The esterification of carboxylic acid with alcohol over hydrous zirconium oxide.

K Takahashi, M Shibagaki, H Matsushita

Index: Takahashi, Kyoko; Shibagaki, Makoto; Matsushita, Hajime Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 7 p. 2353 - 2361

Full Text: HTML

Citation Number: 61

Abstract

The esterification of carboxylic acids with alcohols proceeded efficiently with hydrous zirconium oxide to give the corresponding esters in the vapor phase, in the liquid phase, and in an autoclave. The steric hindrance of carboxylic acids and alcohols affected the esterification by lowering the reactivity. With a rise in the reaction temperature, the conversion of the carboxylic acid increased. The dehydration of alcohols was prevented ...

Related Articles:

Nonactin biosynthesis: the initial committed step is the condensation of acetate (malonate) and succinate

[Nelson, Michael E.; Priestley, Nigel D. Journal of the American Chemical Society, 2002 , vol. 124, # 12 p. 2894 - 2902]

Silver Acetate Mediated Acetoxylations of Alkyl Halides

[Nolla-Saltiel, Roberto; Carrillo-Arcos, Ulises Alonso; Porcel, Susana Synthesis (Germany), 2014 , vol. 46, # 2 p. 165 - 169]

Microwave??Assisted NiCl2 Promoted Acylation of Alcohols

[Constantinou-Kokotou, Violetta; Peristeraki, Anna Synthetic Communications, 2004 , vol. 34, # 22 p. 4227 - 4232]

N-Acyl 1, 5-diazabicyclo [4.3. 0] non-5-ene (DBN) tetraphenylborate salts as O-acylating agents

[Taylor, James E.; Williams, Jonathan M.J.; Bull, Steven D. Tetrahedron Letters, 2012 , vol. 53, # 32 p. 4074 - 4076]

In situ generated Ph 3 P (OAc) 2 as a novel reagent for the efficient acetylation of alcohols and thiols at room temperature

[Tetrahedron Letters, , vol. 54, # 14 p. 1813 - 1816]

More Articles...