Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

SES Martin, DA Watson

Index: Martin, Sara E. S.; Watson, Donald A. Journal of the American Chemical Society, 2013 , vol. 135, # 36 p. 13330 - 13333

Full Text: HTML

Citation Number: 18

Abstract

Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.

Related Articles:

Synthesis and reactions of silanes containing two triflate groups

[Matyjaszewski, K.; Chen, Y. L. Journal of Organometallic Chemistry, 1988 , vol. 340, p. 7 - 12]

Proton addition to silylstyrenes: Overcoming the predilection for protiodesilylation

[Henry, Courtney; Brook, Michael A. Tetrahedron, 1994 , vol. 50, # 39 p. 11379 - 11390]

Zur chemie der perfluoralkansulfonsäuren

[Schmeisser, M.; Sartori, P.; Lippsmeier, B. Chemische Berichte, 1970 , vol. 103, p. 868 - 879]

Phenylenbis (silandiyl??triflate) als neuartige Synthesebausteine für vielfältig strukturierte Organosilizium??Polymere

[Uhlig, Wolfram Helvetica Chimica Acta, 1994 , vol. 77, p. 972 - 980]

Transformations of diallylsilanes under the action of electrophilic reagents

[Suslova, Elena N.; Albanov, Alexandr I.; Shainyan, Bagrat A. Journal of Organometallic Chemistry, 2009 , vol. 694, # 3 p. 420 - 426]

More Articles...