Carbohydrate Research
2001-05-18
LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds.
J S Yadav, B V Reddy, L Chandraiah, K S Reddy
Index: Carbohydr. Res. 332(2) , 221-4, (2001)
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Abstract
The treatment of glycals with allyltrimethylsilane in the presence of lithium tetrafluoroborate in acetonitrile gave the corresponding allyl 2,3-unsaturated C-glycosylic compounds in excellent yields with high anomeric selectivity.
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