Inorganica Chimica Acta

Crystal structures of Pt (II) and Pd (II) complexes with the free radical 4-aminoTEMPO

C Tessier, FD Rochon

Index: Tessier, Christian; Rochon, Fernande D. Inorganica Chimica Acta, 2010 , vol. 363, # 11 p. 2652 - 2660

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Citation Number: 3

Abstract

Pt (II) and Pd (II) compounds containing the free radical 4-aminoTEMPO (4amTEMPO) were synthesized and characterised by X-ray diffraction methods. The disubstituted complexes cis- and trans-Pt (4amTEMPO) 2I2 were studied. The trans isomer was prepared from the isomerisation of the cis analogue. The two Pd (II) compounds trans-Pd (4amTEMPO) 2X2 (X= Cl and I) were also characterised by crystallographic methods. A mixed-ligand ...