Journal of the American Chemical Society 2008-10-29

Synthesis of beta-, gamma-, and delta-lactams via Pd(II)-catalyzed C-H activation reactions.

Masayuki Wasa, Jin-Quan Yu

Index: J. Am. Chem. Soc. 130(43) , 14058-9, (2008)

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Abstract

Pd(II)-catalyzed intramolecular amination of sp2 and sp3 C-H bonds are developed using a combination of CuCl2 and AgOAc as the oxidant. The reaction protocol tolerates the presence of a double bond in the substrates. This catalytic reaction provides practical access to a wide range of beta-, gamma-, and delta-lactams.

Related Compounds

  • Silver acetate

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