Tetrahedron letters

Reductive dehalogenation of halophenols in sulfite–bisulfate medium

S Adimurthy, G Ramachandraiah

Index: Adimurthy, Subbarayappa; Ramachandraiah, Gadde Tetrahedron Letters, 2004 , vol. 45, # 27 p. 5251 - 5252

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Citation Number: 10

Abstract

In recent years, the halogens on aromatic rings have been used as potential protecting or blocking groups in synthetic organic chemistry. [1] and [2] Aromatic halides are readily reduced by metal-catalyzed transfer hydrogenolysis. 3 The process of reductive elimination of halogens from aromatic rings is relatively quite a difficult task. There are reports of the use of Pd(II) salts, to give the corresponding dehalogenated compounds. 4 Generally, debrominations ...

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