Journal of the American Chemical Society

Two-photon chemistry in the laser jet: photoionization of the diphenylmethyl radical generated by Norrish type I photocleavage of benzhydryl phenyl ketone

W Adam, RS Oestrich

Index: Adam, Waldemar; Oestrich, Rolf Schulte Journal of the American Chemical Society, 1992 , vol. 114, # 15 p. 6031 - 6034

Full Text: HTML

Citation Number: 13

Abstract

Abstract: It is shown that in the laser jet (LJ) mode (argon ion laser) the benzhydryl phenyl ketone (1) undergoes a twephoton reaction in CCl, to yield benzhydryl chloride. The one- photon products are 1, 1, 2, 2-tetraphenylethane (3), benzophenone, and 1, l, l-trichloro-2, 2- diphenylethane (4). In methanol, on the other hand, our results suggest even a three-photon reaction in which benzhydryl methyl ether (5) is produced besides the one-photon ...

Related Articles:

Selective and efficient alcoholyses of allylic, secondary-and tertiary benzylic alcohols in the presence of iron (III)

[Salehi, Peyman; Iranpoor, Nasser; Behbahani, Farahnaz Kargar Tetrahedron, 1998 , vol. 54, # 5-6 p. 943 - 948]

Williamson reaction in ionic liquids

[Xu, Zhen Yuan; Xu, Dan Qian; Liu, Bao You Organic Preparations and Procedures International, 2004 , vol. 36, # 2 p. 156 - 161]

Simple and Direct sp3 C–H Bond Arylation of Tetrahydroisoquinolines and Isochromans via 2, 3-Dichloro-5, 6-dicyano-1, 4-benzoquinone Oxidation under Mild …

[Muramatsu, Wataru; Nakano, Kimihiro; Li, Chao-Jun Organic Letters, 2013 , vol. 15, # 14 p. 3650 - 3653]

THE PREPARATION OF 2, 3-DICYANO-5, 6-DICHLOROQUINONE (DDQ)

[Muramatsu, Wataru; Nakano, Kimihiro Organic Letters, 2014 , vol. 16, # 7 p. 2042 - 2045]

Photochemical reaction of 1, 4-naphthalenedicarbonitrile with alkylbenzenes and bibenzyls

[Albini, Angelo; Fasani, Elisa; Mella, Mariella Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 4119 - 4125]

More Articles...