Synthesis and Structure of Oligomeric Dimesitylgermyl-Substituted Carbodiimides; Characterization of Higher Oligomers

M Dahrouch, M Rivière-Baudet, J Satgé…

Index: Dahrouch, Mohamed; Riviere-Baudet, Monique; Satge, Jacques; Mauzac, Monique; Cardin, Christine J.; Thorpe, James H. Organometallics, 1998 , vol. 17, # 4 p. 623 - 629

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Citation Number: 16

Abstract

New cyclic oligomers of dimesitylgermylene carbodiimides (Mes2GeNCN) n (n= 3 (1) and 4 (2)) were synthesized by reactions of dimesityldichlorogermane with either cyanamide in the presence of triethylamine or lithium cyanamide. The reactions always gave 1, the trimer of hypothetical (Mes2Ge N-CN), as the major compound. Higher oligomers 3 (n up to 20-30) also can be isolated depending on the reaction conditions. In THF solution at room ...

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