The Journal of organic chemistry

Constructing the OCF2O Moiety Using BrF3

Y Hagooly, S Rozen

Index: Rozen, Shlomo; Mishani, Eyal Journal of the Chemical Society, Chemical Communications, 1994 , # 18 p. 2081 - 2082

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Citation Number: 15

Abstract

A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination

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