Aminocarbonylation of (Hetero) aryl Bromides with Ammonia and Amines using a Palladium/DalPhos Catalyst System

PG Alsabeh, M Stradiotto, H Neumann…

Index: Alsabeh, Pamela G.; Stradiotto, Mark; Neumann, Helfried; Beller, Matthias Advanced Synthesis and Catalysis, 2012 , vol. 354, # 16 p. 3065 - 3070

Full Text: HTML

Citation Number: 17

Abstract

Abstract Variants of the DalPhos [2-aminophenylbisadamantyl) phosphine] ligand family were examined in a palladium-catalyzed carbonylative amination reaction using inexpensive carbon monoxide and ammonia as reagents. As a result of this survey, the Pyr- DalPhos ligand was identified as being effective for the selective aminocarbonylation of aryl bromides with ammonia, as well as primary and secondary alkylamines. A variety of ...

Related Articles:

Palladium-1, 10-phenanthroline complex encaged in Y zeolite: An efficient and highly recyclable heterogeneous catalyst for aminocarbonylation

[Mei, Hui; Hu, Jianglin; Xiao, Se; Lei, Yizhu; Li, Guangxing Applied Catalysis A: General, 2014 , vol. 475, p. 40 - 47]

Solvent free, N, N′-carbonyldiimidazole (CDI) mediated amidation

[Verma, Sanjeev K.; Ghorpade, Ramarao; Pratap, Ajay; Kaushik Tetrahedron Letters, 2012 , vol. 53, # 19 p. 2373 - 2376]

Electrochemical synthesis of amides: direct transformation of methyl ketones with formamides

[Huang, Haolai; Yuan, Gaoqing; Li, Xianwei; Jiang, Huanfeng Tetrahedron Letters, 2013 , vol. 54, # 52 p. 7156 - 7159]

Double carbonylation of aryl iodides with diethylamine catalyzed by dinuclear palladium complexes

[Journal of Organometallic Chemistry, , vol. 687, # 2 p. 436 - 443]

Preparation of amides mediated by isopropylmagnesium chloride under continuous flow conditions

[Munoz, Juan De M.; Alcazar, Jesus; De La Hoz, Antonio; Diaz-Ortiz, Angel; Alonso De Diego, Sergio-A. Green Chemistry, 2012 , vol. 14, # 5 p. 1335 - 1341]

More Articles...