Angewandte Chemie (International Edition)
2003-11-03
Difluoromethyl phenyl sulfone as a selective difluoromethylene dianion equivalent: one-pot stereoselective synthesis of anti-2,2-difluoropropane-1,3-diols.
G K Surya Prakash, Jinbo Hu, Thomas Mathew, George A Olah
Index: Angew. Chem. Int. Ed. Engl. 42th ed., 42 , 5216-5219, (2003)
Full Text: HTML
Abstract
Related Articles:
Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: probing the hard/soft nature of fluorinated carbanions.
2008-08-01
[J. Org. Chem. 15th ed., 73 , 5699-5713, (2008)]
Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.
2003-05-30
[J. Org. Chem. 11th ed., 68 , 4457-4463, (2003)]
Facile synthesis of chiral alpha-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines.
2005-09-12
[Angew. Chem. Int. Ed. Engl. 36th ed., 44 , 5882-5886, (2005)]
Nucleophilic difluoromethylation of primary alkyl halides using difluoromethyl phenyl sulfone as a difluoromethyl anion equivalent.
2004-11-11
[Org. Lett. 23th ed., 6 , 4315-4317, (2004)]
Stereoselective synthesis of di- and monofluoromethylated vicinal ethylenediamines with di- and monofluoromethyl sulfones.
2007-04-13
[J. Org. Chem. 8th ed., 72 , 3119-3121, (2007)]