Synthesis

Amination of (η3-Allyl) dicarbonylnitrosyliron Complexes: A Route to γ-Amino-α, β-unsaturated Carboxylic Acid Derivatives

S Nakanishi, K Okamoto, H Yamaguchi, T Takata

Index: Nakanishi, Saburo; Okamoto, Kenji; Yamaguchi, Hiroshi; Takata, Toshikazu Synthesis, 1998 , # 12 p. 1735 - 1741

Full Text: HTML

Citation Number: 0

Abstract

Abstract: Amines reacted regioselectively with (η3-allyl) dicarbonylnitrosyliron complexes having ester group on the allyl ligand to give γ-amino-α, β-unsaturated esters in high yields. A remarkable effect of the substituents attached to the allyl ligand was observed on the reaction rate and regioselectivity of the amination. The methoxycarbonyl group significantly accelerates the reaction rate and enhances the regioselectivity of the reaction. The phenyl ...

Related Articles:

Lewis Acid Mediated [2, 3]-Sigmatropic Rearrangement of Allylic α-Amino Amides

[Blid, Jan; Brandt, Peter; Somfai, Peter Journal of Organic Chemistry, 2004 , vol. 69, # 9 p. 3043 - 3049]

Tsuji–Trost N??Allylation with Allylic Acetates by Using a Cellulose–Palladium Catalyst

[Vaddula, Buchi Reddy; Saha, Amit; Varma, Rajender S.; Leazer, John European Journal of Organic Chemistry, 2012 , # 34 p. 6707 - 6709]

Synthesis of Allylamines fromAlkynes and Iminium Ions

[Rehn, Susanne; Ofial, Armin R.; Mayr, Herbert Synthesis, 2003 , # 12 p. 1790 - 1796]

Reductive amination of aldehydes and ketones with sodium triacetoxyborohydride. studies on direct and indirect reductive amination procedures1

[Abdel-Magid, Ahmed F.; Carson, Kenneth G.; Harris, Bruce D.; Maryanoff, Cynthia A.; Shah, Rekha D. Journal of Organic Chemistry, 1996 , vol. 61, # 11 p. 3849 - 3862]

Metallic bismuth and tantalum mediated C-allylation of aldimines with allyl bromide

[Bhuyan, Pulak J.; Prajapati, Dipak; Sandhu, Jagir S. Tetrahedron Letters, 1993 , vol. 34, # 49 p. 7975 - 7976]

More Articles...