Chemistry Letters

Dealuminoxylation of aluminum allyl or benzyl alkoxides and deoxygenation of allyl ethers by lithium aluminum hydride in the presence of titanium catalyst.

F Sato, Y Tomuro, H Ishikawa, T Oikawa, M Sato

Index: Sato, Fumie; Tomuro, Yasuji; Ishikawa, Hiroaki; Oikawa, Takeshi Chemistry Letters, 1980 , p. 103 - 106

Full Text: HTML

Citation Number: 9

Abstract

Various aluminum allyl and benzyl alkoxides and allyl ethers undergo hydrogenolysis by LiAlH 4 in the presence of a catalytic amount of TiCl 4 or Cp 2 TiCl 2. Thus, the present reaction provides a convenient method for replacing oxygen-containing functional groups at the allylic or benzylic position by hydrogen.

Related Articles:

Selective hydrogenation by a novel palladium (II) complex

[Kerr, James M.; Suckling, Colin J. Tetrahedron Letters, 1988 , vol. 29, # 43 p. 5545 - 5548]

Nickel??catalyzed Asymmetric Alkylation of Some Chiral and Achiral Allylic Alcohols. Preliminary communication

[Consiglio, Giambattista; Morandini,Franco; Piccolo, Oreste Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 987 - 989]

1-hexene oligomerization in liquid, vapor, and supercritical phases over beidellite and ultrastable Y zeolite catalysts

[Pater, Jerome P. G.; Jacobs, Pierre A.; Martens, Johan A. Journal of Catalysis, 1998 , vol. 179, # 2 p. 477 - 482]

Nickel??catalyzed Asymmetric Alkylation of Some Chiral and Achiral Allylic Alcohols. Preliminary communication

[Consiglio, Giambattista; Morandini,Franco; Piccolo, Oreste Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 987 - 989]

Novel neutral arylnickel (II) phosphine catalysts containing 2-oxazolinylphenolato N–O chelate ligands for ethylene oligomerization and propylene dimerization

[Zhao, Wei; Qian, Yanlong; Huang, Jiling; Duan, Jianjun Journal of Organometallic Chemistry, 2004 , vol. 689, # 16 p. 2614 - 2623]

More Articles...