Liebigs Annalen der Chemie

(Cycloalkylmethyl) bis (η5??cyclopentadienyl) titan (III)??Komplexe

H Lehmkuhl, S Fustero

Index: Lehmkuhl, Herbert; Fustero, Santos Liebigs Annalen der Chemie, 1980 , # 9 p. 1361 - 1370

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Abstract

Abstract Bei der Reaktion von Bis (cyclopentadienyl) titandichlorid (1) und Isopropylmagnesiumbromid (2) mit den Methylencycloalkanen 3–8 (Cyclopropan), 35 (Cyclobutan) und 37 (Cyclopentan) entstehen die (Cycloalkylmethyl) bis (cyclopentadienyl) titan (III)-Verbindungen 9–14, 36 und 38. Bei mindestens einer geminalen Dimethylsubstitution sind die Cyclopropylmethyl-Komplexe 12–14 stabil. Bei fehlender ...

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