Tetrahedron Letters

Staudinger/aza-Wittig reactions utilizing a novel linear polymer-supported triphenylphosphine as a modified liquid-phase reagent

H Mahdavi, J Amani

Index: Mahdavi, Hossein; Amani, Javad Tetrahedron Letters, 2009 , vol. 50, # 43 p. 5923 - 5926

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Citation Number: 13

Abstract

A new triphenylphosphine reagent linked to a linear maleimide-styrene copolymer is synthesized and is found to be effective for the formation of a variety of imines via the Staudinger/aza-Wittig reaction. This linear polymer-supported triphenylphosphine has a unique solubility behavior and provides for a simple means of purifying the desired imine from the phosphine oxide by-product. The reactivity of this polymeric reagent is superior to ...

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